New outcomes of Lewis base addition to diboranes(4): electronic effects override strong steric disincentives
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چکیده
منابع مشابه
New outcomes of Lewis base addition to diboranes(4): electronic effects override strong steric disincentives.
Two surprising new outcomes of the reaction of Lewis bases with dihalodiboranes(4) are presented, including sp(2)-sp(3) diboranes in which the Lewis base unit is bound to a highly sterically congested boron atom, and a rearranged double base adduct. The results provide a fuller understanding of the reactivity of diboranes, a poorly-understood class of molecule of critical importance to syntheti...
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ژورنال
عنوان ژورنال: Chemical Communications
سال: 2016
ISSN: 1359-7345,1364-548X
DOI: 10.1039/c6cc01493c